Uses
Structure of gaseous barium acetylacetonate.
Barium acetylacetonate has been examined in metal organic chemical vapour deposition of BaTiO3 thin films.[3] The related complex with hexafluoroacetylacetonate Ba(hfa)2(tetraglyme) has also been investigated. Its formation of a sublimable adduct containing a polyether illustrates the high coordination numbers typical of barium.[4]
References
- ↑ Paw, Witold; Baum, Thomas H.; Lam, Kin-Chung; Rheingold, Arnold L. (2000). “Low-Melting, Mononuclear Tetrahydrofuran Complexes of M(2,2,6,6-tetramethylheptane-3,5-dionate)2 (M = Ba, Sr) and Related Analogues”. Inorganic Chemistry. 39 (9): 2011–2014. doi:10.1021/ic990641z. PMID 11428125.
- ↑ Rossetto, G.; Polo, A.; Benetollo, F.; Porchia, M.; Zanella, P. (1992). “Studies on molecular barium precursors for MOCVD: Synthesis and characterization of barium 2,2,6,6-tetramethyl-3,5-heptanedionate. X-ray crystal structure of [Ba(THD)2·Et2O]2″. Polyhedron. 11 (8): 979–985. doi:10.1016/S0277-5387(00)83351-3.
- ↑ Schulz, Douglas L.; Neumayer, Deborah A.; Marks, Tobin J. (1997). Volatile β-Diketonate Complexes of Calcium(II), Strontium(II), and Barium(II). Inorganic Syntheses. Vol. 31. pp. 1–7. doi:10.1002/9780470132623.ch1. ISBN 9780470132623.