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Iron tetrafluoride is a binary inorganic compound with the chemical formula FeF4.[1] It was initially observed in 2003 via mass spectrometry and Fourier-transform infrared spectroscopy.[2] Iron tetrafluoride is assumed to have tetrahedral or square planar structure.[2] It has been calculated to be stable in the gas phase.[3]

Iron tetrafluoride can be prepared by reaction of iron with fluorine in excess neon and argon at 4 K:[2][4]

Fe + 2F2 → FeF4

References

  1. ^ Russian Journal of Physical Chemistry. British Library Lending Division. July 1992. p. 1389. Retrieved 12 February 2024.
  2. ^ a b c Comprehensive Inorganic Chemistry II: From Elements to Applications. Newnes. 23 July 2013. p. 199. ISBN 978-0-08-096529-1. Retrieved 12 February 2024.
  3. ^ Haupt, Axel (22 March 2021). Organic and Inorganic Fluorine Chemistry: Methods and Applications. Walter de Gruyter GmbH & Co KG. p. 297. ISBN 978-3-11-065950-4. Retrieved 12 February 2024.
  4. ^ Schlöder, Tobias; Vent-Schmidt, Thomas; Riedel, Sebastian (26 November 2012). “A Matrix-Isolation and Quantum-Chemical Investigation of FeF 4”. Angewandte Chemie International Edition. 51 (48): 12063–12067. doi:10.1002/anie.201206464. ISSN 1433-7851. PMID 23097315. Retrieved 12 February 2024.