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Sodium deuteroxide or deuterated sodium hydroxide is a chemical compound with the formula NaOD or NaO2H. IUPAC recommends that the symbol for deuterium should be 2H,[2] although most chemists use the term NaOD. It is a white solid very similar to sodium hydroxide, of which it is an isotopologue. It is used as a strong base and deuterium source in the production of other deuterated compounds. For example, reaction with chloral hydrate gives deuterated chloroform,[3] and reaction with N-nitrosodimethylamine gives the deuterated analog of that compound.[4][full citation needed] Sodium deuteroxide is an ionic compound, consisting of sodium cations Na+ and deuteroxide anions OD or O2H.

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References

  1. ^ “Sodium deuteroxide”. Sigma aldrich. Retrieved 30 April 2021.
  2. ^ “Provisional Recommendations”. Nomenclature of Inorganic Chemistry. Chemical Nomenclature and Structure Representation Division. IUPAC. § IR-3.3.2. Archived from the original on 27 October 2006. Retrieved 2024-08-01.
  3. ^ Breuer, F. W. (1935). “Chloroform-d (Deuteriochloroform)”. Journal of the American Chemical Society. 57 (11): 2236–2237. Bibcode:1935JAChS..57.2236B. doi:10.1021/ja01314a058.
  4. ^ National Cancer Institute (U.S.) (1973). Journal (51 ed.). the University of Michigan.